Tegafur and 5-Fluorouracil pelvic tissues concentrations in rectal cancer patients treated with preoperative chemoradiation. The processed sample stability investigation and their impact in the reability of data

L. Zufía(1), A. Aldaz(1), A. Ortega(1), F. Calvo(2), J. Giráldez(1)

(1) Pharmacy Department, University Hospital of Navarra; (2) Oncology Department, Hospital General Universitario Gregorio Marañón

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Tegafur (Ftorafur), 1-(tetrahydro-2-furanyl)-5-fluorouracil, a oral prodrug of 5-fluorouracil (known radiopotentiating agent in preclinical models), has an efficacy similar to that of intravenous 5-Fu. Clinical experiences have explored with success the feasibility, tolerance and tumor response rate of oral Tegafur administered simultaneously with preoperative radiotherapy in rectal cancer [ 1] .

Objectives: The aim of this study was to measure Tegafur and 5-Fu concentrations in tissues of rectal cancer patients treated with preoperative chemoradiation and to correlate drug concentrations with cancer downstanging effects. Also was conducted a little stability study.

Patients and methods: Three tissue samples of 16 patients with locally advanced rectal cancer treated with preoperative pelvic irradiation sensitized with oral Tegafur before surgery (5 to 6 weeks after the completion of chemoradiation) were analyzed. Seven patients received a precharge dose of Tegafur 24 hours before surgery. Tegafur and 5-Fu concentrations, were determined according to a high performance liquid chromatography (HPLC) method developed and validated by the pharmacokinetic laboratory of the Pharmacy Department at the University Hospital of Navarra [ 2] . Stability study of processed samples was investigated, as a requirement of the analytical method validation, by reinjecting the samples (hold at room temperature in the auto-injector) at different time intervals during 16 days.

Results: In eight of the nine patients without precharge dose was possible obtained detectable levels of Tegafur but only in one patient 5-Fu levels were detectables. In Tegafur pre-charged patients both Tegafur and 5-Fu were present in all tissue samples with exception of 2 fat samples. Both, Tegafur and 5-Fu levels were higher in tumor samples than other sites and show a clear tendency toward a correlation between degree of 5-Fu present in the residual tumor and cancer downstaging. Stability study showed a progressive increase of 5-Fu levels with time with no change in Tegafur values; so we hypothesize about the presence of a chemically labile metabolic intermediates that spontaneously cleave to 5-Fu.

Conclusion: A prospective study with a larger cohort of patients is necessary to confirm these results and to evaluate if tumor uptake of fluoropyrimidine could be a prognostic indicator of downstanging. Research should also be required to characterize the metabolic intermediates found in the stability study.

References:
[ 1] F.A. Calvo, M. Gomez-Espi, J.A. Diaz-Gonzalez, et al. Intraoperative presacral electron boost following preoperative chemoradiation in T3-4Nx rectal cancer: initial local effects and clinical outcome analysis. Radiother. Oncol. 2002; 62:201-06.
[ 2] L. Zufia, A. Aldaz, C. Castellanos, et al. Determination of 5-fluorouracil and its prodrug Tegafur in plasma and tissue by high-performance liquid chromatography in a single injection: validation for application in clinical pharmacokinetic studies. Ther. Drug Monit. 2003; 25:221-8.

Reference: PAGE 14 () Abstr 825 [www.page-meeting.org/?abstract=825]

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